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UNIPLEX M8M

                                        Melamine Molybdate

                                        CAS RN 65235-34-9

 

Description:                A fire and smoke suppressant additive for flexible and rigid PVC compounds.  This product may be also useful in a number of different polyolefin and polyamide applications as a synergist with melamine-based non-halogen flame retardants.

Applications:

                                    Rigid and Flexible PVC compounds

                                    Flexible halogenated alloys (e.g. PVC/PVDF)

                                    Non-halogen Polyolefinic compounds

                                    Non-halogen glass-filled Nylon compounds

 

 

Typical Properties:

            Molybdenum Content (%)                    45 min.

            Thermal Stability (5% Loss)                  >300°C

 

Solubility (g/100g Solvent at 25°C):

            Water                                                               Insoluble

            Acetone                                                           Insoluble

            Isopropanol                                                      Insoluble

            Xylene                                                              Insoluble

            Tetrahydrofuran                                                Insoluble

 

General Specifications:

Appearance                                                      Off-white Powder

Particle Size, D97, Laser Diffraction                   5 microns max.

pH,5 % in Water                                              5 - 8    

Loss on Drying (2 hr, 135°C)                           0.5 max.

 

Health & Safety:        Refer to Material Safety Data Sheet (MSDS).


Application Data:

This product is useful in both rigid and flexible formulations of halogenated vinyl resins as a replacement for Ammonium octamolybdate as a smoke suppressant. Increased oxygen indices are also found indicating improved flame resistance.

 

Uniplex M8M was compounded into rigid PVC at 200°C with Geon 30 PVC, 2 phr Microthene 510 Lubricant, 2 phr Tin Thioglycolate Stabilizer and 2 phr Uniplex M8M. The compound was compression molded and subjected to various tests with the results tabulated in Table 1.

 

TABLE 1  RIGID PVC COMPOUNDS

 

Example

Loading (phr)

Molybdenum compound

Thermal Stability (5% Loss TGA)

Comound Thermal Stability (min)

Oxygen Index

%Smoke Reduction (Dmc in ASTM E-662)

Control

None

---

>120

45

----

Uniplex M8M

2

380°C

>120

49

87

 

Flexible PVC(Geon 30) compounds were prepared by dry blending additives with Geon 30 PVC and then compounding in a two roll mill at 160°C. The compounds were compression molded and tested. The results are tabulated in Table 2. The general purpose formula used was:

 

MATERIAL

LOADING (phr)

Geon 30 PVC

100

Uniplex 546-A

34

Uniplex FRP-45

40

Molybdate complex

2.5

Antimony Trioxide

2

Lead Stabilizer (Dythal XL)

7

 

TABLE 2 FLEXIBLE PVC COMPOUNDS

 

Example

Loading (phr)

Molybdenum compound

Thermal Stability (5% Loss TGA)

Compound Thermal Stability (min)

Oxygen Index

%Smoke Reduction (Dmc in ASTM E-662)

Control

None

---

>120

34

----

AOM

5

290°C

>120

39

30

Uniplex M8M

5

380°C

>120

41

35

 

 

These suggestions and data are based on information we believe to be reliable. They are offered in good faith, but without guarantee, as conditions and methods of use of our products are beyond our control. We recommend that the prospective user determine the suitability of our materials and suggestions before adopting them on a commercial scale. Suggestions for uses of our product should not be understood as recommendations that they be used in violation of any
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