UNIPLEX M8M
Melamine Molybdate
CAS RN 65235-34-9
Description:
A fire and smoke suppressant additive for flexible and rigid PVC
compounds. This product may be also
useful in a number of different polyolefin and polyamide applications as a
synergist with melamine-based non-halogen flame retardants.
Applications:
Rigid and Flexible PVC compounds
Flexible halogenated alloys (e.g. PVC/PVDF)
Non-halogen Polyolefinic compounds
Non-halogen glass-filled Nylon compounds
Typical Properties:
Molybdenum Content (%)
45 min.
Thermal Stability (5% Loss)
>300°C
Solubility
(g/100g Solvent at 25°C):
Water
Insoluble
Acetone
Insoluble
Isopropanol
Insoluble
Xylene
Insoluble
Tetrahydrofuran
Insoluble
General Specifications:
Appearance
Off-white Powder
Particle
Size, D97, Laser Diffraction
5 microns max.
pH,5
% in Water
5 - 8
Loss
on Drying (2 hr, 135°C)
0.5 max.
Health & Safety:
Refer to Material Safety Data Sheet (MSDS).
Application Data:
This
product is useful in both rigid and flexible formulations of halogenated vinyl
resins as a replacement for Ammonium octamolybdate as a smoke suppressant.
Increased oxygen indices are also found indicating improved flame resistance.
Uniplex
M8M was compounded into rigid PVC at 200°C with Geon 30 PVC, 2 phr Microthene 510 Lubricant,
2 phr Tin Thioglycolate Stabilizer and 2 phr Uniplex M8M. The compound was
compression molded and subjected to various tests with the results tabulated in
Table 1.
|
Example |
Loading (phr) Molybdenum compound |
Thermal Stability (5% Loss TGA) |
Comound Thermal Stability (min) |
Oxygen Index |
%Smoke Reduction (Dmc in ASTM E-662) |
|
Control |
None |
--- |
>120 |
45 |
---- |
|
Uniplex
M8M |
2 |
380°C |
>120 |
49 |
87 |
Flexible
PVC(Geon 30) compounds were prepared by dry blending additives with Geon 30 PVC
and then compounding in a two roll mill at 160°C.
The compounds were compression molded and tested. The results are tabulated in
Table 2. The general purpose formula used was:
|
MATERIAL |
LOADING (phr) |
|
Geon
30 PVC |
100 |
|
Uniplex
546-A |
34 |
|
Uniplex
FRP-45 |
40 |
|
Molybdate
complex |
2.5 |
|
Antimony
Trioxide |
2 |
|
Lead
Stabilizer (Dythal XL) |
7 |
TABLE 2
FLEXIBLE PVC COMPOUNDS
|
Example |
Loading (phr) Molybdenum compound |
Thermal Stability (5% Loss TGA) |
Compound Thermal Stability (min) |
Oxygen Index |
%Smoke Reduction (Dmc in ASTM E-662) |
|
Control |
None |
--- |
>120 |
34 |
---- |
|
AOM |
5 |
290°C |
>120 |
39 |
30 |
|
Uniplex
M8M |
5 |
380°C |
>120 |
41 |
35 |