UNIPLEX BAP-370
FLAME RETARDANT
Tris (tribromoneopentyl) phosphate
CAS: 19186-97-1
Uniplex BAP-370 is used primarily in
Polypropylene molding applications for UL94 V-2 ratings. This rating can be
achieved by using 4-6 phr Uniplex BAP-370 with 2-3 phr Antimony Trioxide as a
synergist.
Uniplex BAP-370 is non-reactive with
the typical hindered amine light stabilizers (HALS) used polypropylene fiber
applications. In fiber applications, 3-4 phr Uniplex BAP-370 with 1-2 phr Sb2O3 will pass a California 701 burn test.
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APPLICATIONS IN
POLYESTER
COMPARISON OF
FLAME RETARDANTS
FR CONCENTRATION FOR UL-94 V-0
(1.6mm)
2/1 POLYCARBONATE/PET ALLOY
|
Flame Retardant |
% Bromine |
% Phosphorus |
% Minimum |
|
Great Lakes BC-52 |
51.3 |
- - - |
12 |
|
Triphenyl Phosphate |
- - - |
9.5 |
13 |
|
Uniplex BAP-370 |
70 |
3 |
6 |
FLAME RETARDANCY COMPARISON PC/PBT ALLOY AT 12% FR
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PHOSPHORUS IN MINERAL-FILLED PBT
|
PBT, Mineral Filled |
84 |
84 |
|
Great Lakes BC-52 |
16 |
- - - |
|
Uniplex BAP-370 |
- - - |
16 |
|
Oxygen Index |
29.1 |
35.0 |
|
UL-94 Rating (1/16") |
Burns |
V-0 |
FLAME RETARDANCY IN GLASS-FILLED PET
|
PET, 30% Glass |
80 |
80 |
|
Uniplex BAP-370 |
15 |
20 |
|
Sodium Antimonate Teflon 6C |
5 |
- - - |
|
Teflon 6C |
0.5 |
0.5 |
|
Oxygen Index |
29.4 |
36.0 |
|
UL-94 Rating (1/16") |
V-2 |
V-0 |
APPLICATIONS IN POLYVINYL CHLORIDE (PVC)
SEMI-RIGID PVC
FORMULATION
|
Component |
Parts |
|
PVC Resin |
100 |
|
Lead Stabilizer |
3 |
|
Epoxidized Soya Oil |
3 |
|
Alumina Trihydrate |
5 |
|
Antimony Trioxide |
3 |
|
Diisodecyl Phthalate |
17 |
|
Dioctyl Azelate |
17 |
|
Uniplex BAP-370 |
6 |
PROPERTIES
|
Oxygen Index |
32.0 |
|
Shore A Hardness |
19 |
|
Shore D Hardness |
46 |
|
Tensile Strength, psi Unaged Aged (7 days/100° C) % Retention |
2950 3000 102 |
|
Elongation, % Unaged Aged (7 days/100° C) % Retention |
230 210 91 |
|
Low Temperature Flex, ° C |
-16 |
HIGH TEMPERATURE WIRE AND CABLE APPLICATION
FORMULATION
|
Component |
phr |
|
PVC Resin (Geon 301) |
100 |
|
Lead Stabilizer |
5 |
|
Uniplex FRP-45 |
40 |
|
Uniplex 546-A (TOTM) |
34.3 |
|
Uniplex BAP-370 |
Varied |
|
Antimony Trioxide |
15 |
PHYSICAL PROPERTIES
|
UL 1581-105° C RATING |
No Uniplex BAP-370 |
2 phr Uniplex BAP-370 |
|
Tensile Modulus at 100% Strain (psi) |
1760 |
1754 |
|
Tensile Strength at Break |
2050 |
2064 |
|
Elongation (%) |
278 |
280 |
|
Shore A Hardness |
88 |
89 |
FLAMMABILITY TESTING
|
Oxygen Index |
33 |
38.9 |
|
NBS Smoke Values (ASTM E662) |
|
|
|
Smoldering (DMC) |
180 |
140 |
|
Flaming (DMC) |
440 |
360 |
|
Weight Loss 24 hours/90° C |
0.2 |
0.2 |
APPLICATIONS IN THERMOPLASTIC RESINS
FORMULATION
|
Component |
phr |
|
Poly(2,6-Dimethyl-1,4-phenylene ether) |
30 |
|
Polythiophenylene1 |
70 |
|
Hydrogenated Styrene-butadiene-Styrene |
|
|
block copolymer2 |
10 |
|
Uniplex BAP-370 |
6 |
|
Antimony Trioxide |
2 |
1 Ryton M-2588 2 Kraton G-1651
|
Property |
Result |
|
Flexural Modulus |
2500 MPa |
|
IZOD Impact Strength |
101 MPa |
|
Heat Distortion Temperature |
150° C |
|
UL 94 Rating |
V-0 |
TOXICOLOGICAL PROPERTIES
|
Skin Absorption |
LD50 > 5000 mg/kg Rat |
|
Inhalation |
LC50 > 1.81 mg/L Rat, 4 hr, max
conc. |
|
Ingestion |
LD50 > 5000 mg/kg Rat |
|
Skin Sensitization |
Negative in Buehler Assay |
|
Gene Mutation |
Ames Test - Negative |
|
Sub-Chronic Toxicity |
No toxic effects and pathology after dietary
administration of up to 20,000 ppm in rats for 28 days |
ECOLOGICAL PROPERTIES
|
Environmental Effects |
|
|
Rainbow Trout |
96 hr LC50 > 100 ppm |
|
Daphnia |
48 hr EC50 > 100 ppm |
|
Algae |
72 hr EC50 > 100 ppm |
These suggestions and data are based
on information we believe to be reliable. They are offered in good faith, but
without guarantee, as conditions and methods of use of our products are beyond
our control. We recommend that the prospective use determine the suitability of
our materials and suggestions before adopting them on a commercial scale.
Suggestions for uses of our product should not be understood as recommendations
that they be used in violation of any patents.