MATERIAL
SAFETY DATA SHEET
1.
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Uniplex FP-760 D (20% Dispersion in Water)
Synonyms:
Fluoroalkyl Phosphate Dispersion in Water
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MANUFACTURER: |
EMERGENCY
TELEPHONE NUMBERS: |
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Unitex
Chemical Corporation |
Emergency Telephone Number:
CHEMTREC 1
(800) 424-9300 |
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International 1 (703) 527-3887 |
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520
Broome Road |
Telephone
Number for Information: |
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P.O.
Box 16344 |
(336)
378-0965 (Monday - Friday
8:00 a.m. - 5:00 p.m.) |
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Greensboro,
NC 27406 |
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2.
COMPOSITION/INFORMATION ON INGREDIENTS
Components
% (optional)
OSHA PEL
ACGIH TLV
CAS NO.
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Fluoroalkyl
(C8-12 ) Phosphate (Di/Mono) 20%
65530-64-5
Diethanolamine Salt 65530-63-4
(contains
3% Diethanolamine)
111-42-2 |
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Water
80%
7732-18-5
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3. HAZARDS
IDENTIFICATION
Emergency
Overview: Do not breathe vapors; do not ingest; avoid
contact with skin, eyes, or clothing. Wash
thoroughly after handling; do not eat, drink, or smoke in work areas.
Potential
Health Effects: May cause skin irritation.
Inhalation of dust may cause irritation to the respiratory tract.
Inhalation of large amounts of respirable particles may be toxic to lungs,
symptoms may be modest at first; followed by severe shortness of breath
requiring prompt medical attention.
Eye
Contact: May cause burning sensation, irritation
accompanied with pain and corneal or conjunctival ulceration in severe cases.
Skin
Contact: May cause irritation, stinging, redness, and some
swelling.
Ingestion: May cause severe burning in the mouth and
digestive tract.
Chronic: None known.
4.
FIRST AID MEASURES
Inhalation: Remove to fresh air if coughing, soreness in
respiratory tract, chest tightness, or difficulty in breathing occurs. If breathing is difficult, give oxygen and seek prompt
medical attention.
Eye
Contact: Immediately flush with large quantities of water
for at least 15 minutes, while holding the eyelids open.
Do not attempt to neutralize with chemical agents.
Contact a physician if irritation persists.
Skin
Contact: Immediately remove contaminated clothing and
flush area with large quantities of water for at least 15 minutes. Contact a physician if irritation persists.
Ingestion: If patient is conscious, give several glasses of
water for dilution effect and contact a physician.
Do not induce vomiting. Do
not give an unconscious person anything by mouth.
Note to Physicians: Activated charcoal
mixture may be administered. To
prepare activated charcoal mixture, suspend 50 grams activated charcoal in 400
ml water and mix thoroughly. Administer
5 ml/kg, or 350 ml for an average adult.
5.
FIRE FIGHTING MEASURES
Flash
Point: >93°C
(>199°F)
Cleveland open cup.
General Hazard:
Hazardous decomposition products including carbon dioxide, carbon
monoxide, hydrogen fluoride, toxic gases or particles may be formed
during combustion. These
products may cause severe eye, nose, throat, and lung irritation or toxic
effects.
Fire
Fighting Instructions: Extinguishing media--water fog or spray; carbon
dioxide; foam; or earth and mud. Wear
self-contained breathing apparatus.
Hazardous
Combustion Products:
Oxides of Carbon, Hydrogen fluoride, and other potentially
toxic
gases or particles. Avoid breathing
decomposition products.
6.
ACCIDENTAL RELEASE MEASURES
Land
Spill: Scrape up spilled material and dispose in
accordance with all local, state, and federal regulations.
If molten, allow to solidify then scrape up spill.
Water
Spill: Remove product layered on water by mechanical
means. Place spill in appropriate
container for disposal in approved facilities.
7.
HANDLING AND STORAGE
Storage
Temperature:
Ambient
Storage Pressure:
Pressureless
General: Store in cool, dry, and well-ventilated area.
Keep containers closed. Keep
away from
open
flames and heated surfaces above 200°C (392°F).
Avoid circumstances that produce respirable particles unless suitable
ventilation and respirator are used.
8. EXPOSURE
CONTROL/PERSONAL PROTECTION
Engineering
Controls: Keep container tightly closed.
Use only with adequate ventilation.
Vent heated extruder or dryer fumes outside work area.
Do not form aerosols. Minimize
worker exposure to mists, sprays, and dusts.
Personal
Protection: Splash-proof goggles with rubber, PVC, or
impervious chemical gloves.
Respirator: None required.
Use NIOSH organic vapor cartridge respirator with dust caps, as
appropriate.
Protective
Clothing: Impervious chemical clothing for remediation of
large spills.
Exposure
Guideline Comments: No AEL has been established for this product.
Other products
with
fluorinated material components have AEL of 0.1 mg/m3 (8 hour TWA) for respirable size particles.
9. PHYSICAL AND
CHEMICAL PROPERTIES
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Vapor Pressure : |
ND
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Vapor Density (Air = 1) : |
ND
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Specific Gravity : |
ND
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Evaporation Rate : |
<1
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Solubility in Water : |
Dispersible
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Melting Point : |
NA
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pH : |
7-9
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Odor : |
Characteristic
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Boiling Point : |
ND
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Appearance : |
Light
brown liquid |
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Viscosity : |
ND
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Physical State : |
Liquid
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10. STABILITY AND REACTIVITY
General: Stable
Incompatible
Materials and Conditions to Avoid: None known
Hazardous
Decomposition: Carbon dioxide, carbon monoxide, hydrogen fluoride,
toxic gases or particles may be formed during combustion.
These products may cause severe eye, nose, throat, and lung irritation or
toxic effects.
11. TOXICOLOGICAL INFORMATION
Oral ALD 7,500 mg/kg in rats. The product caused non-specific effects such as weight loss
and
irritation in animals exposed
by ingestion. Based on related
products, inhalation of spray or mist
may cause nasal, throat, or
lung irritation. Inhalation of
large amounts of respirable particles
may be toxic to the lungs.
Symptoms may be modest initially, followed in hours by severe
shortness of breath requiring
prompt medical attention.
Carcinogenicity
Information: None
of the components present in this material at concentrations
equal to or greater than
0.1% are listed by IARC, NTP, OSHA, AGCIH as a carcinogen.
12. ECOLOGICAL INFORMATION
None
known.
13. DISPOSAL CONSIDERATIONS
This
product is registered by TSCA. The
product should be incinerated, according to state Federal regulations.
14. TRANSPORT INFORMATION
Nonhazardous;
not regulated by DOT. RQ is 3300
pounds (as is).
15. REGULATORY INFORMATION
This
product is registered by TSCA. This
product is not an acute hazardous substance as defined by Title III Hazard
Classification Sections 311,312 (the product contains 3% by weight
Diethanolamine).
16. OTHER INFORMATION
No
specific notes.
MSDS
Status: Update to ANS1 Z 400.1-1993
Format.
HAZARD RATINGS
NFPA
HMIS
Health
1
1
Flammability 1
1
Reactivity
0 0
Revision
Summary:
10/28/02
Jim Day CAS revision
2/6/03
Jim Day Correction Section 15
1/16/04 Jim Day Stated RQ & Diethanolamine content.
This information is furnished without warranty, expressed or implied. The data in this MSDS relates only to the specific material designated therein. Unitex Chemical Corporation assumes no legal responsibility for use or reliance upon this data. This form complies with OSHA's Hazard Communication Standard, 29 CFR 1910.1200.