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MATERIAL SAFETY DATA SHEET

 

 

1.    CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

 

        Product Name:    Uniplex 110

        Synonyms:   Dimethyl Phthalate/DMP

 

MANUFACTURER:

EMERGENCY TELEPHONE NUMBERS:

 

 

Unitex Chemical Corporation

Emergency Telephone Number:   CHEMTREC    1 (800) 424-9300

 

                                                         International  1 (703) 527-3887

520 Broome Road

Telephone Number for Information:

P.O. Box 16344

(336) 378-0965  (Monday - Friday  8:00 a.m. - 5:00 p.m.)

Greensboro, NC   27406

 

 

                                                                                                                                                                                   

 

2.    COMPOSITION/INFORMATION ON INGREDIENTS

 

Components                                                                    % (optional)                OSHA PEL                 ACGIH TLV                  CAS NO.

 

Dimethyl Phthalate                                             > 99                         5mg/m3            5mg/m3                131-11-3

 

 

 

 

 

                                                                                                                                                                                   

 

3.    HAZARDS IDENTIFICATION

 

Emergency Overview:    Clear, oily liquid, may be irritating to mucous membranes and eyes; can cause central nervous system depression when ingested.  Normally, not irritating to, or absorbed through the skin.

 

Potential Health Effects:    High vapor concentrations are irritating to nose, throat, lungs, and eyes.  May cause depression of central nervous system, if swallowed.

 

Eye Contact:    Irritating, but no permanent damage if washed out from eyes promptly with water.

 

Skin Contact:    May be mildly irritating to the skin.

 

Ingestion:    DO NOT INGEST.  May cause central nervous sytem depression.

 

Chronic:    ND (Not determined)

 

 

 

4.    FIRST AID MEASURES

 

Inhalation:    Remove victim to fresh air; give artificial respiration if breathing has stopped.  Get medical attention promptly.

 

Eye Contact:    Flush eyes with large amounts of water until irritation subsides.  If irritation persists, get medical attention.

 

Skin Contact:    Wash thoroughly with soap and water.  Remove contaminated clothing and wash before reuse.  If irritation persists, get medical attention.

 

Ingestion:     If swallowed, do not induce vomiting; get prompt medical attention.

                                                                                                                                                                                  

 

5.    FIRE FIGHTING MEASURES

 

      Flash Point:  295F (COC)

 

General Hazard:    Uniplex 110 will burn if involved in fire; Carbon Dioxide and Carbon Monoxide will be formed upon combustion.

 

Fire Fighting Instructions:    Extinguish with water fog or spray, CO2, dry chemical, foam, or earth/mud.  DO NOT use direct water stream, as material will be spread--treat as burning oil.

 

Hazardous Combustion Products:   Carbon Dioxide, Carbon Monoxide.

                                                                                                                                                                                  

 

6.    ACCIDENTAL RELEASE MEASURES

 

Land Spill:    Notify appropriate authorities immediately if Reportable Quantity (RQ) of 5000 lb. (2270 Kg) is exceeded.  Contain spill and pump into containers for disposal.  Avoid runoff into sewers and storm drains.

Contain small spills and absorb with an inert material, such as sand or vermiculite.

 

Water Spill:    Remove from water surface by skimming or with suitable absorbents, such as straw.

                                                                                                                                                                                   

 

7.    HANDLING AND STORAGE

 

Storage Temperature:          Ambient                   Storage Pressure:         Pressureless

 

General:    General warehousing conditions are satisfactory for this material.

                                                                                                                                                                                  


 

8.    EXPOSURE CONTROL/PERSONAL PROTECTION

 

Engineering Controls:    Local exhaust ventilation is recommended to keep exposure below limits--see Section 2 for exposure guidelines.

 

Personal Protection:    If concentrations are over exposure limit, use OSHA-approved respirator.

 

Respirator:    Use OSHA-approved respirator if concentrations are above exposure limits--See Section 2.

 

Protective Clothing:    Splash proof goggles and vinyl, or rubber gloves.  Exercise good chemical handling practice.

                                                                                                                                                                                  

 

9.    PHYSICAL AND CHEMICAL PROPERTIES

 

Vapor Pressure         :

<0.01 mm at 20C     

Vapor Density (Air = 1) :

6.61                                  

 

Specific Gravity         :

Approx. 1.190             

Evaporation Rate          :

< 1 (Butyl Acetate = 1)     

 

Solubility in Water      :

0.43 g/100ml              

Freezing Point              :

Approx. 0C                      

 

pH                              :

NA                              

Odor                             :

Mild, characteristic ester  

Boiling Point               :

136C at 5 mm Hg     

 

odor                                  

 

Viscosity                    :

Approx. 14-15 cps      

Appearance                  :

Clear, oily liquid                

 

 

 

Physical State              :

Liquid                                

 

                                                                                                                                                                                  

 

10.  STABILITY AND REACTIVITY

 

General:    Stable under normal warehousing, handling, and use conditions.

 

Incompatible Materials and Conditions to Avoid:    Strong oxidizing agents.

 

Hazardous Decomposition:    Carbon Dioxide and Carbon Monoxide.

                                                                                                                                                                                  

 

11.  TOXICOLOGICAL INFORMATION

 

Oral LD50 (Rat): 6.9 ml/Kg. Dermal LD50 (Rabbit): > 10 ml/Kg (highest dose tested).

Skin Sensitization (Guinea Pig):  None.  Skin sensitization (Human);  None.

Eye Irritation (Rabbit):  Slight.  Eye Irritation (Human):  Slight.

                                                                                                                                                                                  

 

12.  ECOLOGICAL INFORMATION

 

BOD (5-day):  1.18g oxygen/g.  COD:  1.7g oxygen/g.

Acute Aquatic Effects:  48 hour  EC-50 (daphnia): > 52 ml/L

                                      96 hour LC-50 (Fathead Minnow):  120 mg/L

 

                                                                                                                                                                                   



13.  DISPOSAL CONSIDERATIONS

 

Incineration by a permitted hazardous waste facility in accordance with all local, state, and

federal regulations is the preferred method of disposal.

                                                                                                                                                                                  

 

 

 

 

 

 

 

14.  TRANSPORT INFORMATION

 

DOT shipping Name: "Environmentally Hazardous Substance, Liquid, N.O.S., 9, UN 3082,

  PG III, RQ (Dimethyl Phthalate)".

Hazard Class:  9      Identification No. UN 3082

Emergency Response Guide #171

IMDG Status:  Not Regulated

TDG (Canada):  Not Regulated

                                                                                                                                                                                  

 

15.  REGULATORY INFORMATION

 

OSHA Status:  This product is a hazardous chemical under 29 CFR 1200.

TSCA Status:  Registered on TSCA Inventory

CERCLA Reportable Quantity:  5000lb. (2270 Kg)

SARA Title III:

     Section 302   Extremely Hazardous Substances:  None

     Sections 311/312   Hazard Categories:  Immediate Health Hazard/Delayed Health Hazard

     Section 313   Toxic Chemicals:  Reportable

RCRA Status:  Hazardous Waste Code U102.

California Proposition 65:  Not included on the list of chemicals known to the State to cause

                                           cancer or reproductive toxicity.

Massachusetts Substance List:  Dimethyl Phthalate

New Jersey Workplace Hazardous Substance List:  Dimethyl Phthalate

Pennsylvania Hazardous Substance list:  Dimethyl Phthalate.

WHMIS (Canada) Ingredient Disclosure list:  Dimethyl Phthalate.

WHMIS (Canada) Status:  Non controlled

                                                                                                                                                                                  

 

16.  OTHER INFORMATION

 

Dimethyl Phthalate is not listed by IARC, ACGIH, NTP, or OSHA as a carcinogen.

 

                                                                                 HAZARD RATINGS

                                                                                 NFPA             HMIS

                                             Health                           1                    1

                                             Flammability                1                    1

                                             Reactivity                     0                    0

Revision Summary: 

1/7/97 - Update to 1996 North American Emergency Response Guidebook

3/11/97 - J. Day

1/26/98 - J. Day

8/3/98 - J. Day (Area Code Chg.)

5/11/04 – J. Day

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