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MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Uniplex 105
Synonyms: Diethyl Phthalate, DEP
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MANUFACTURER: |
EMERGENCY TELEPHONE NUMBERS: |
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Unitex Chemical Corporation |
Emergency Telephone Number: CHEMTREC 1 (800) 424-9300 |
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International 1 (703) 527-3887 |
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520 Broome Road |
Telephone Number for Information: |
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P.O. Box 16344 |
(336) 378-0965 (Monday - Friday 8:00 a.m. - 5:00 p.m.) |
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Greensboro, NC 27406 |
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2. COMPOSITION/INFORMATION ON INGREDIENTS
Components % (optional) OSHA PEL ACGIH TLV CAS NO.
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Diethyl Phthalate > 99 None Established 5mg/m3 84-66-2 |
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3hr TWA |
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3. HAZARDS IDENTIFICATION
Emergency Overview: Clear, oily liquid, may be irritating to mucous membranes and eyes; can cause central nervous system depression when ingested. Normally, not irritating to, or absorbed through the skin.
Potential Health Effects: High vapor concentrations are irritating to nose, throat, lungs, and eyes. May cause depression of central nervous system, if swallowed.
Eye Contact: Irritating, but no permanent damage if washed out from eyes promptly with water.
Skin Contact: May be mildly irritating to the skin.
Ingestion: DO NOT INGEST. May cause central nervous system depression.
Chronic: ND (Not determined)
4. FIRST AID MEASURES
Inhalation: Remove victim to fresh air; give artificial respiration if breathing has stopped. Get medical attention promptly.
Eye Contact: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention.
Skin Contact: Wash thoroughly with soap and water. Remove contaminated clothing and wash before reuse. If irritation persists, get medical attention.
Ingestion: If swallowed, do not induce vomiting; get prompt medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 295F (COC)
LEL (368°F) 0.7%
General Hazard: Uniplex 105 will burn if involved in fire; Carbon Dioxide and Carbon Monoxide will be formed upon combustion.
Fire Fighting Instructions: Extinguish with water fog or spray, CO2, dry chemical, foam, or earth/mud. DO NOT use direct water stream, as material will be spread--treat as burning oil.
Hazardous Combustion Products: Carbon Dioxide, Carbon Monoxide.
6. ACCIDENTAL RELEASE MEASURES
Land Spill: Contain spill and pump into containers for disposal. Avoid runoff into sewers and storm drains. Contain small spills and absorb with an inert material, such as sand or vermiculite.
Water Spill: Remove from water surface by skimming or with suitable absorbents, such as straw.
7. HANDLING AND STORAGE
Storage Temperature: Ambient Storage Pressure: Pressureless
General: General warehousing conditions are satisfactory for this material.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Engineering Controls: Local exhaust ventilation is recommended to keep exposure below limits--see Section 2 for exposure guidelines.
Personal Protection: If concentrations are over exposure limit, use OSHA-approved respirator.
Respirator: Use OSHA-approved respirator if concentrations are above exposure limits--See Section 2.
Protective Clothing: Splash proof goggles and vinyl, or rubber gloves. Exercise good chemical handling practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
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Vapor Pressure : |
0.002 mm at 77°F |
Vapor Density (Air = 1) : |
ND |
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Specific Gravity : |
Approx. 1.12 |
Evaporation Rate : |
< 1 (Butyl Acetate = 1) |
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Solubility in Water : |
0.1% at 77°F |
Freezing Point : |
-41°F |
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pH : |
NA |
Odor : |
Mild, characteristic ester |
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Boiling Point : |
298°C |
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odor |
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Viscosity : |
ND |
Appearance : |
Clear, oily liquid |
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Physical State : |
Liquid |
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10. STABILITY AND REACTIVITY
General: Stable under normal warehousing, handling, and use conditions.
Incompatible Materials and Conditions to Avoid: Strong oxidizing agents.
Hazardous Decomposition: Carbon Dioxide and Carbon Monoxide.
11. TOXICOLOGICAL INFORMATION
LD50 (Rat): > 5000mg/Kg intraperitoneal injection.
Skin Sensitization (Guinea Pig): None. Skin sensitization (Human); None.
Eye Irritation (Rabbit): Slight. Eye Irritation (Human): Slight.
12. ECOLOGICAL INFORMATION
BOD (5-day): 1.18g oxygen/g. COD: 1.7g oxygen/g.
Acute Aquatic Effects: 48 hour EC-50 (daphnia): > 41 ml/L
13. DISPOSAL CONSIDERATIONS
Incineration by a permitted hazardous waste facility in accordance with all local, state, and
federal regulations is the preferred method of disposal.
14. TRANSPORT INFORMATION
DOT shipping Name: "Environmentally Hazardous Substance, Liquid, N.O.S., 9, UN 3082,
PG III, RQ (Diethyl Phthalate)".
Hazard Class: 9 Identification No. UN 3082
Emergency Response Guide #171
IMDG Status: Not Regulated
TDG (Canada): Not Regulated
15. REGULATORY INFORMATION
OSHA Status: This product is a hazardous chemical under 29 CFR 1200.
TSCA Status: Registered on TSCA Inventory
SARA Title III:
Section 302 Extremely Hazardous Substances: None
Sections 311/312 Hazard Categories: Immediate Health Hazard/Delayed Health Hazard
Section 313 Toxic Chemicals: Reportable
RCRA Status: Hazardous Waste Code U102.
California Proposition 65: Not included on the list of chemicals known to the State to cause
cancer or reproductive toxicity.
Massachusetts Substance List: Diethyl Phthalate
New Jersey Workplace Hazardous Substance List: Diethyl Phthalate
Pennsylvania Hazardous Substance list: Diethyl Phthalate.
WHMIS (Canada) Ingredient Disclosure list: Diethyl Phthalate.
WHMIS (Canada) Status: Noncontrolled
DSL Status: Registered on DSL Inventory (Canada)
EINECS No.: 201-550-6
ENCS No.: 3-1301X (Japan)
ECL Serial No.: 3-1035 (Korea)
16. OTHER INFORMATION
Diethyl Phthalate is not listed by IARC, ACGIH, NTP, or OSHA as a carcinogen.
HAZARD RATINGS
NFPA HMIS
Health 1 1
Flammability 1 1
Reactivity 0 0
Revision Summary:
1/7/97 - Update to 1996 North American Emergency Response Guidebook
3/11/97 - J. Day
1/26/98 - J. Day
8/3/98 - J. Day (Area Code Chg.)
5/11/04 – Jim Day